Application of Four-Element Raney Ni in Catalytic Hydrogenation of Aliphatic Low-carbon Nitro Compounds
YANG Yu-chun1， HU Chang-fa2， NI Ping1
1. Jiaxing Center of Green Chemistry and Engineering, Chinese Academy of Sciences, Jiaxing 314006, China; 2. Sinochem International Corporation, Shanghai 200121, China
Abstract：Aliphatic low-carbon nitro compounds were catalytic hydrogenated using four-element Raney Ni(Ni-Al-Mo-Fe) as the catalyst. The effect of compostion and size of the catalyst to the hydrogenation was investigated. The results showed that 100 mesh~150 mesh Ni-Al-Mo-Fe(Ni%>90%) was the most suitable catalyst for the hydrogenation with the yields of 95%, and the conversion rates were more than 99%．
杨玉淳， 胡昌法， 倪平. 四元骨架镍在脂肪族低碳硝基化合物催化氢化还原反应中的应用[J]. 合成化学, 2015, 23(10): 960-962.
YANG Yu-chun， HU Chang-fa， NI Ping. Application of Four-Element Raney Ni in Catalytic Hydrogenation of Aliphatic Low-carbon Nitro Compounds. Chinese Journal of Synthetic Chemistry, 2015, 23(10): 960-962.
2015, Vol. 23 
