Abstract：A novel ligand， 7-｛［2-(8-Hydroxyquinolin-7-yl)-1H-benzo［d］imidazole-1-yl］methyl｝quinolin-8-ol(H2L), was synthesized by condensation reaction of 8-hydroxyquinoline-7-carbaldehyde with o-phenylenediamine． Two novel metal complexes, ZnL·H2O(1)and Al2L3·3H2O(2), were synthesized by coordination reaction of H2L with Ac2Zn·2H2O and AlCl3·6H2O， respectively. The structures and properties were characterized by UV-Vis, 1H NMR, IR, elemental analysis and FL. λem of 1and 2 were 514 nm(λex=400 nm) and 525 nm(λex=401 nm), respectively.
刘鸿， 李创海， 廖亚四. 7-{2-［1-（8-羟基喹啉-7-亚甲基）］苯并咪唑基}-8-羟基喹啉-及其金属配合物的合成与荧光性能[J]. 合成化学, 2015, 23(12): 1120-1123.
LIU Hong, LI Chuang-hai, LIAO Ya-si. Synthesis and Fluorescent Properties of 7-｛［2-(8-Hydroxyquinolin-7-yl)-1H-benzo［d］imidazole-1-yl]-methyl｝quinolin-8-ol and Its Metal Complexes. Chinese Journal of Synthetic Chemistry, 2015, 23(12): 1120-1123.
2015, Vol. 23 
