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| Synthesis of a Novel Phenanthroline Derivative |
| LI Rong1a, WANG Qiang1a, ZHANG Deng-qing1a, LI Xian-ying1b, XIANG Yun-jie1a, JIN Wu-song1a |
| a. College of Chemistry, Chemical Engineering and Biotechnology; b. School of Environmental Science and Engineering, 1. Donghua University, Shanghai 201620, China |
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Abstract 2,2′-【2,5-bis｛2-［2-（2-methoxyethoxy)ethoxy］ethoxy｝-1,4-phenylene】bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane(6) was prepared by a two-step reaction from 2-［2-（2-methoxyethoxy)ethyl］-1,4-methylbenzene sulfonate. A novel phenanthroline derivative, 3,3′-【2,5-bis｛2-［2-（2-methoxyethoxy)ethoxy］ethoxy｝-1,4-phenylene】bis(1,10-phenanthrdin), was synthesized by Suzuki coupling reaction of 3-bromo-1,10-phenanthrdine with 6. The stucture was characterized by 1H NMR and MALDI-TOF-MS.
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Received: 29 December 2014
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2015, Vol. 23 
